We collected data on 768 metabolites from four tissues including nonembryogenic staged calli (NEC), primary embryogenic calli (PEC), initiation staged globular embryos (GE)[1], Green Fiber (GF), and Green Fiber Dark (GFD)[2]. Differentially accumulated metabolites (DAMs) were defined as those exhibiting a fold change ≥ 2 or a fold change ≤ 0.5 and a variable importance in project (VIP) ≥ 1 between PEC versus NEC, GE versus PEC, GE versus NEC, or GF versus GFD (p < 0.05). In total, 156, 139, 159, and 236 DAMs were collected. User can get metabolite data or DAMs data by selecting the metabolite category.